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Table 3

List of symbols.

Symbol Description S.I. Units
A Projected surface of the particle m2
Ci,b Concentration of the specie i in the bulk solution mol m−3
Ci,s Concentration of the specie i at the external surface of the solid mol m−3
Di Molecular diffusivity of the specie i m2 s−1
Mi Molar mass of the specie i g mol−1
P Perimeter of the projected surface of the particle m
R Universal gas constant J mol−1 K−1
Re Reynolds number
Rp Particle radius m
Sc Scriven number
Sh Sherwood number
T Temperature K
Vl Volume of liquid m3
fe External resistance to mass transfer ratio
ji Diffusion flow of the specie i in the external diffusion layer mol m−2s−1
kd,i Mass transfer conductance of the specie i in the external diffusion layer m s−1
knc Non-catalyzed chemical reaction constant m s−1
mi Mass of the specie i kg
n Partial order relating to nitric acid in the non-catalyzed chemical reaction
m s−1
r Dissolution rate check mol m−2 s−1
kg m−2 s−1
rnc Non-catalyzed chemical reaction rate m s−1
Dissolution rate of swinging between chemical and diffusional control m s−1
t Time s
Δl Displacement of the solid/liquid interface m
νi Stoichiometric coefficient of the specie i
ρi Density of the specie i kg m−3

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