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Impacts of molecular architecture on the radiation-induced degradation and reaction kinetics of hydrophobic diglycolamides with the solvated electron and the dodecane radical cation
Michaela R. Bronstetter, Gregory P. Horne, Andrew R. Cook, Stephen P. Mezyk, Joseph R. Wilbanks, Bobby Layne, Alyssa Gaiser and Jacy K. Conrad Physical Chemistry Chemical Physics 27(30) 16254 (2025) https://doi.org/10.1039/D5CP01332A
Radionuclides measurements using Raman spectrometers for the analysis of advanced nuclear reprocessing
Evaluation of the Arrhenius behavior of n-dodecane radical cation (RH˙+) reactivity with lanthanide ion-complexed N,N,N′,N′-tetraoctyl diglycolamide (TODGA)
Maya H. Rogalski, Anh N. Dang and Stephen P. Mezyk Physical Chemistry Chemical Physics 27(4) 1960 (2025) https://doi.org/10.1039/D4CP03633F
Effect of Europium Complexation on N,N,N′,N′-Tetraoctyldiglycolamide Degradation Against Gamma Radiation
Influence of the Experimental Conditions on the Radiolytic Stability of N, N, N',N'-Tetraoctyldiglycolamide (TODGA)
Iván SÁNCHEZ-GARCÍA, Hitos GALÁN, Ana NÚÑEZ, Jose Manuel PERLADO and Joaquín COBOS Progress in Nuclear Science and Technology 8 280 (2025) https://doi.org/10.15669/pnst.8.280
Influence of the gamma source on the radiolytic stability of N,N,N′,N′-tetra-n-octyl-diglycolamide (TODGA)
Ken Verguts, Karen Van Hecke, Jan Jordens, Stefan Voorspoels and Thomas Cardinaels Radiochimica Acta 113(2) 125 (2025) https://doi.org/10.1515/ract-2024-0329
Early-stage oxidation and subsequent damage of the used nuclear fuel extractant TODGA; electron pulse radiolysis and theoretical insights
Effect of f-element complexation on the radiolysis of 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP])
Stephen P. Mezyk, Makayla Baxter, Cristian Celis-Barros, Travis S. Grimes, Peter R. Zalupski, Cathy Rae, Christopher A. Zarzana, Andrew R. Cook and Gregory P. Horne Dalton Transactions 53(16) 6881 (2024) https://doi.org/10.1039/D4DT00424H
Radiolytic stability and effects on metal extraction of N,N,N′-trioctyldiglycolamide, an important TODGA degradation product
Iván Sánchez-García, Richard J. M. Egberink, Willem Verboom and Hitos Galán New Journal of Chemistry 48(5) 2087 (2024) https://doi.org/10.1039/D3NJ04265K
Studies for mutual solubility of TODGA and water at 298.15 K and 0.1 MPa
TODGA-DOHyA: Physicochemical Insights into a Stable Solvent System for Nuclear Reprocessing
Parvathy Narayanan, Satyabrata Mishra, K Rama Swami, Thonakot Prathibha, Desigan Narasimhan, Ramesh L Gardas and K A Venkatesan Journal of Chemical & Engineering Data 69(3) 721 (2024) https://doi.org/10.1021/acs.jced.3c00359
Gamma radiolysis studies of N,N-dioctyl-2-hydroxyacetamide: Complexation effect on the stability and implications on the hydrometallurgical extraction performance
Gamma Radiolysis of Phenyl-Substituted TODGAs: Part II
Christopher A. Zarzana, Jack McAlpine, Andreas Wilden, Michelle Hupert, Andrea Stärk, Mudassir Iqbal, Willem Verboom, Aspen N. Vandevender, Bruce J. Mincher, Gary S. Groenewold and Giuseppe Modolo Solvent Extraction and Ion Exchange 41(5) 582 (2023) https://doi.org/10.1080/07366299.2023.2221290
Radiolytic evaluation of acetohydroxamic acid (AHA) under biphasic (HNO3:n-dodecane and TBP/DEHBA/DEHiBA) used nuclear fuel reprocessing conditions
Interinstitutional Study of the New EURO-GANEX Process Resistance by Gamma Irradiation Test Loops
Ivan Sanchez-Garcia, Xavier Heres, Dean. R. Peterman, Hitos Galan, Sylvain Costenoble, Sylvain Broussard, Johann Sinot, Travis S. Grimes, Kash Reid Anderson, Santa Jansone-Popova, Maria Chiara Gullo, Alessandro Casnati, Andreas Wilden and Andreas Geist Industrial & Engineering Chemistry Research 62(47) 20326 (2023) https://doi.org/10.1021/acs.iecr.3c02884
Low and High LET Degradation Studies of Metal-Loaded Organic Phase Ligands in the ALSEP Process
Impact of lanthanide ion complexation and temperature on the chemical reactivity of N,N,N′,N′-tetraoctyl diglycolamide (TODGA) with the dodecane radical cation
Gregory P. Horne, Cristian Celis-Barros, Jacy K. Conrad, Travis S. Grimes, Jeffrey R. McLachlan, Brian M. Rotermund, Andrew R. Cook and Stephen P. Mezyk Physical Chemistry Chemical Physics 25(24) 16404 (2023) https://doi.org/10.1039/D3CP01119D
Effect of metal complexation on diglycolamide radiolysis: a comparison between ex situ gamma and in situ alpha irradiation
Ashleigh Kimberlin, Georges Saint-Louis, Dominique Guillaumont, et al. Physical Chemistry Chemical Physics 24(16) 9213 (2022) https://doi.org/10.1039/D1CP05731F
An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, Part 2 — homogeneous recycling
Development of experimental irradiation strategies to evaluate the robustness of TODGA and water-soluble BTP extraction systems for advanced nuclear fuel recycling